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These plastics can be almost endlessly remelted, held at temp, etc., if done gently.
With a heat gun, I'd hesitate to go too far past 250°F/115°C too quickly until I was comfortable with the material.
Plastic WILL begin to burn and permanently deteriorate at 350-400°F or so.
Silicone can handle up to 400-500°F.
(Get a cast iron pot or pan to roughly 250°F/110°C, then invert and put a silicone cookie sheet on it to make a work surface that will make life waaaaaay easier. Preheat the device along with the pan for a few minutes, too.)